Thermoelectric materials: Current challenges and prospects
Materiales termoeléctricos: Retos actuales y perspectivas.
How to cite:
Abstract:
Thermoelectric (TE) materials make it possible to convert temperature differences directly into electrical energy, or vice versa, through the Seebeck and Peltier effects. Their applications range from waste heat recovery to cooling and thereby contribute to reducing energy losses and environmental impact, making them attractive for the energy transition. Currently, strategies such as nanostructuring, the employment of new non.toxic and abundant materials, as well as the use of artificial intelligence and machine learning to predict new materials and optimize parameters before synthesis are driving the development of more sustainable and efficient alternatives, consolidating TE materials as a technology with great potential in the energy and industrial fields.
Keywords: thermoelectric materials; thermoelectric effects; figure of merit; sustainable materials; artificial intelligence in materials.
Adam, A., Ibrahim, E., Panbude, A., Jayabal, K., Veluswamy, P., & Diab, A. (2021). Thermoelectric power properties of Ge doped PbTe alloys. Journal of Alloys and Compounds, 872, 159630. https://doi.org/10.1016/j.jallcom.2021.159630
Al-Fartoos, M., Roy, A., Mallick, T., & Tahir, A. (2023). Advancing Thermoelectric Materials: A Comprehensive Review Exploring the Significance of One-Dimensional Nano Structuring. Nanomaterials, 13(13), 2011. https://doi.org/10.3390/nano13132011
Bell, L. (2008). Cooling, Heating, Generating Power, and Recovering Waste Heat with Thermoelectric Systems. Science, 321(5895), 1457–1461. https://doi.org/10.1126/science.1158899
Cao, T., Shi, X., Li, M., Hu, B., Chen, W., Liu, W., Lyu, W., MacLeod, J., & Chen, Z. (2023). Advances in bismuth-telluride-based thermoelectric devices: Progress and challenges. EScience, 3(3), 100122. https://doi.org/10.1016/j.esci.2023.100122
Ceyda, Ö. (2023). Effects of Dimensionality Reduction for High-Efficiency Mg-Based Thermoelectrics. In Magnesium Alloys - Processing, Potential and Applications. IntechOpen. https://doi.org/10.5772/intechopen.110239
Dresselhaus, M., Chen, G., Tang, M., Yang, R., Lee, H., Wang, D., Ren, Z., Fleurial, J., & Gogna, P. (2007). New Directions for Low‐Dimensional Thermoelectric Materials. Advanced Materials, 19(8), 1043–1053. https://doi.org/10.1002/adma.200600527
Du, Y., Xu, J., Paul, B., & Eklund, P. (2018). Flexible thermoelectric materials and devices. Applied Materials Today, 12, 366–388. https://doi.org/10.1016/j.apmt.2018.07.004
Fish, J., Li, C., Fehribach, J., Wolden, C., O’Hayre, R., Bunge, A., & Goodyer, C. (2012). Poisson–Boltzmann model of space charge layer effects on conductivity in randomly distributed nanoionic composites. Electrochimica Acta, 83, 454–462. https://doi.org/10.1016/j.electacta.2012.07.122
Franke, L., Georg, A., Khan, M., Zhang, Q., Long, Z., Brunetti, I., Joglar, M., Lara, A., Simão, C., Geßwein, H., Nefedov, A., Eggeler, Y., Lemmer, U., & Mallick, M. (2024). High Power Density Ag2Se/Sb1.5Bi0.5Te3-Based Fully Printed Origami Thermoelectric Module for Low‐Grade Thermal Energy Harvesting. Advanced Functional Materials, 34(40). https://doi.org/10.1002/adfm.202403646
Goldsmid, H. J. (2016). Introduction to thermoelectricity. Springer.
Gutiérrez Moreno, J. J., Cao, J., Fronzi, M., & Assadi, M. (2020). A review of recent progress in thermoelectric materials through computational methods. Materials for Renewable and Sustainable Energy, 9(3), 16. https://doi.org/10.1007/s40243-020-00175-5
Heremans, J., Cava, R., & Samarth, N. (2017). Tetradymites as thermoelectrics and topological insulators. Nature Reviews Materials, 2(10), 17049. https://doi.org/10.1038/natrevmats.2017.49
Jin, H., Li, J., Iocozzia, J., Zeng, X., Wei, P., Yang, C., Li, N., Liu, Z., He, J. H., Zhu, T., Wang, J., Lin, Z., & Wang, S. (2019). Hybrid Organic–Inorganic Thermoelectric Materials and Devices. Angewandte Chemie International Edition, 58(43), 15206–15226. https://doi.org/10.1002/anie.201901106
Krishna, T., Anil, S., Kodanda, K., Raj, K., & Siva, V. (2021). Analysis of thermoelectric generators in automobile applications. Materials Today: Proceedings, 45, 5835–5839. https://doi.org/10.1016/j.matpr.2020.08.081
Li, D., Gong, Y., Chen, Y., Lin, J., Khan, Q., Zhang, Y., Li, Y., Zhang, H., & Xie, H. (2020). Recent Progress of Two-Dimensional Thermoelectric Materials. Nano-Micro Letters, 12(1), 36. https://doi.org/10.1007/s40820-020-0374-x
Li, J., Huckleby, A., & Zhang, M. (2022). Polymer-based thermoelectric materials: A review of power factor improving strategies. Journal of Materiomics, 8(1), 204–220. https://doi.org/10.1016/j.jmat.2021.03.013
Li, J., Han, Z., Yu, J., Zhuang, H., Hu, H., Su, B., Li, H., Jiang, Y., Chen, L., Liu, W., Zheng, Q., & Li, J. (2023). Wide-temperature-range thermoelectric n-type Mg3(Sb, Bi)2 with high average and peak zT values. Nature Communications, 14(1), 7428. https://doi.org/10.1038/s41467-023-43228-9
Liu, W., Zhang, B., Zhao, L., & Li, J. (2008). Improvement of Thermoelectric Performance of CoSb3−xTex Skutterudite Compounds by Additional Substitution of IVB-Group Elements for Sb. Chemistry of Materials, 20(24), 7526–7531. https://doi.org/10.1021/cm802367f
Muddasar, M., Menéndez, N., Quero, Á., Nasiri, M., Cantarero, A., García, J., Gómez, C., Collins, M. N., & Culebras, M. (2024). Highly-efficient sustainable ionic thermoelectric materials using lignin-derived hydrogels. Advanced Composites and Hybrid Materials, 7(2), 47. https://doi.org/10.1007/s42114-024-00863-0
Muddasar, M., Nasiri, M., Cantarero, A., Gómez, C., Culebras, M., & Collins, M. (2024). Lignin‐Derived Ionic Conducting Membranes for Low‐Grade Thermal Energy Harvesting. Advanced Functional Materials, 34(12). https://doi.org/10.1002/adfm.202306427
Na, G. (2023). Artificial Intelligence for Learning Material Synthesis Processes of Thermoelectric Materials. Chemistry of Materials, 35(19), 8272–8280. https://doi.org/10.1021/acs.chemmater.3c01834
Pan, Y., He, B., Feng, X., Li, F., Chen, D., Burkhardt, U., & Felser, C. (2025). A magneto-thermoelectric with a high figure of merit in topological insulator Bi88Sb12. Nature Materials, 24(1), 76–82. https://doi.org/10.1038/s41563-024-02059-9
Rathnam, L., Suresh, S., Ganguly, A., Singh, N., & Das, G. (2025). Strategies to enhance thermoelectric performance: Review. Journal of Materials Research and Technology, 37, 2694–2717. https://doi.org/10.1016/j.jmrt.2025.06.100
Rogl, G., & Rogl, P. (2017). Skutterudites, a most promising group of thermoelectric materials. Current Opinion in Green and Sustainable Chemistry, 4, 50–57. https://doi.org/10.1016/j.cogsc.2017.02.006
Seebeck, T. J. (1826). Ueber die magnetische Polarisation der Metalle und Erze durch Temperatur‐Differenz. Annalen Der Physik, 82(2), 133–160. https://doi.org/10.1002/andp.18260820202
Shevelkov, A. (2010). Thermoelectric materials: an introduction. Dalton Trans., 39(4), 977–977. https://doi.org/10.1039/B924863N
Shi, X., Wang, L., Lyu, W., Cao, T., Chen, W., Hu, B., & Chen, Z. (2024). Advancing flexible thermoelectrics for integrated electronics. Chemical Society Reviews, 53(18), 9254–9305. https://doi.org/10.1039/D4CS00361F
Singh, R., Dogra, S., Dixit, S., Vatin, N., Bhardwaj, R., Sundramoorthy, A., Perera, H., Patole, S., Mishra, R., & Arya, S. (2024). Advancements in thermoelectric materials for efficient waste heat recovery and renewable energy generation. Hybrid Advances, 5, 100176. https://doi.org/10.1016/j.hybadv.2024.100176
Soumya, S., Fatima, K., Lekshmi, S., Namboothiri, S., Krishnapriya, P., Shreya, V., Harikrishnan, V., Mohan, A., Joh, H., Rani, J., Panwar, V., Sreedhar, K., Jayakumar, P., Samanta, S., Jo, J., & Anoop, G. (2025). Advancements in thermoelectric materials: Emerging trends in organic, inorganic systems, and material informatics. Journal of Alloys and Compounds, 1028, 180661. https://doi.org/10.1016/j.jallcom.2025.180661
Tiryaki, H., Yusuf, A., & Ballikaya, S. (2024). Determination of electrical and thermal conductivities of n- and p-type thermoelectric materials by prediction iteration machine learning method. Energy, 292, 130597. https://doi.org/10.1016/j.energy.2024.130597
Tritt, T., & Subramanian, M. (2006). Thermoelectric Materials, Phenomena, and Applications: A Bird’s Eye View. MRS Bulletin, 31(3), 188–198. https://doi.org/10.1557/mrs2006.44
Wang, J., Yin, Y., Che, C., & Cui, M. (2025). Research Progress of Thermoelectric Materials—A Review. Energies, 18(8), 2122. https://doi.org/10.3390/en18082122
Wang, T., Zhang, C., Snoussi, H., & Zhang, G. (2020). Machine Learning Approaches for Thermoelectric Materials Research. Advanced Functional Materials, 30(5). https://doi.org/10.1002/adfm.201906041
Zhang, H., Li, H., Wang, W., Li, P., Liu, S., Yang, M., & He, C. (2024). Biomass lignin as dispersion to substantially enhance carbon nanotubes thermoelectric converter for energy harvesting. Carbon, 229, 119489. https://doi.org/10.1016/j.carbon.2024.119489
Zhang, P., Lou, Z., Gong, L., Wu, Z., Chen, X., Xu, W., Wang, Y., Xu, J., Dashevsky, Z., & Gao, F. (2023). Development and Applications of Thermoelectric Oxide Ceramics and Devices. Energies, 16(11), 4475. https://doi.org/10.3390/en16114475
